Among all transition metal doped zno dmss co doped zno has attracted much attention not only for its rtfm, but also due to high solubility limit of co in zno and large magnetic moment per co ion. No peaks related to co or cobalt oxides could be discovered from the xrd results, which confirmed the relevant structure of the. In summary, a codoped zno nanoneedle array was fabricated on a silicon substrate by pld method. Synthesis and characterization of co doped zno nanocompound. Electrical transport and optical studies of ferromagnetic cobalt. The photocatalytic activity of the samples was investigated by the degradation of rhodamine b. Request pdf study of diluted magnetic semiconductor. Cathodoluminescence spectra were studied for cr, mn, fe, and codoped samples, among which crdoped zno showed two sharp peaks at 2. Doping is performed by ball milling of 3 wt% of co mixed with zno nanopowders com mercial for. Controlled coii doping of zinc oxide nanocrystals the. Oxygen vacancies and zinc interstitials were found to be the main reasons for roomtemperature ferromagnetism in the codoped zno nps with the support of the results obtained from the epr, photoluminescence, and microraman studies. Nickel ni and cobalt co doped zno nanoparticles were prepared using.
Pdf synthesis and characterization of co doped zno. Pdf undoped and codoped zinc oxide nanoparticles nps and nanorods. The structure of the obtained sample was established by xrd measurements. Cobalt doped zinc oxide nanoparticles nps and nanorods nrs were. Codoped zno we report on the hightemperature ferromagnetism in co doped zno films fabricated by the solgel method above 350 k. Structural and electronic properties of the synthesized material were investigated using xray diffraction and scanning electron microscope, vibrating sample magnetometer vsm, ultraviolet uv spectroscopy and dielectric studies. This fortuitous match between the ionic radii makes a unique materials. Presynthetic doping with 2% co ii results in a 98% quenching of the visible emission of zno, whereas the same quantity doped post synthesis results in only a 60% quenching. We have shown earlier that codoped zno nanoparticles exhibited rtfm by. Study of structural, optical and magnetic properties of cobalt doped. The pure and codoped zno nps showed significant changes in the mh loop where the diamagnetic behavior of zno changes to ferromagnetic nature when doping with co.
Synthesis and characterization of al, co codoped zno. Hrem and xrd results showed that the nanoneedles grew along the caxis with a preferential alignment perpendicular to the substrate. All doped samples exhibited superior photodegradation efficiency than undoped zno. Defectfree transparent conductive zinc tin oxide, adv. Structure, optical properties and synthesis of codoped zno. Pdf diluted magnetic semiconductors with a curie temperature exceeding 300 k are promising. Colloidal cobaltdoped zno nanoparticles by microwave. Roomtemperature ferromagnetic codoped zno nanoneedle. These conditions prove critical to the resulting co ii configuration, which affects both the luminescent and photocatalytic properties of the zno ncs. Ni, co doped zno nanoparticles were prepared by coprecipitation method. Synthesis of doped and undoped zno all chemicals used to prepare pure and cu doped zno were purchased from sigmaaldrich and used without further purification.
Doping efficiency in cobaltdoped zno nanostructured materials. Structural and optical characterization of ni and al codoped zno. Role of cobalt doping on the electrical conductivity of zno. All diffractions match with the hexagonal wurtzite phase of zno pdf 36. Pdf synthesis and characterization of pure and co doped zinc. Preparation and characterization of ni, co doped zno. The co doped zno nanoparticles showed the maximum solubility limit. Effect of cobalt doping on structural, optical, and. Pdf study of structural, optical and magnetic properties of cobalt.
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